It happened just north of the beltline in the 1400-block of Rock Quarry Road during the evening rush.
Police said 32-year-old Pamela Butler was driving southbound when a truck driving northbound, operated by 38-year-old Belsazar Toledo-Garcia, turned left in front of the motorcycle.
Butler was declared dead at the scene.
Toledo-Garcia was not injured. He was charged with misdemeanor death by motor vehicle, driving without a license, and unsafe movement.
Toledo-Garcia was taken to the Wake County Detention Center.
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