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Taloria W. McDonald, 43, of Fayetteville, has been charged with first-degree murder.
McDonald was arrested and booked into the Cumberland County Detention Center without bond.
Officers were dispatched around 7:30 p.m. to 4306 Bragg Boulevard, where there had been a report of a shooting.
When Fayetteville police arrived on the scene, they found a man suffering from a gunshot wound inside his motel room.
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The man was transported to Cape Fear Valley Medical Center where he was pronounced dead.
The victim has been identified as Roger D. Jones, 57, of Fayetteville.
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Detectives with the FPD's Homicide Unit are currently investigating the homicide.