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It happened shortly after 8:10 p.m. on New Hope Road.
Police said Carlos Enrique Berrios, 44, drove his car left of center and collided head-on with a Nissan, driven by Martha Maria Leak.
Berrios, of Water Oak Drive in Raleigh, was pronounced dead at the scene.
Leak, 35, was rushed to WakeMed with serious injuries, police said.
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Police said both Berrios and Leak were wearing seatbelts. Alcohol is not believed to be a factor.
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