Deputies were called to a home in the 6500 block of Sunset Manor Drive around 9:30 p.m.
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Witnesses said the male shooting victim sustained a gunshot wound and fled to a neighbor's house, according to the sheriff's office.
The man was rushed to the hospital and is in critical condition.
After forcing entry, the Tactical Response Team found a woman dead in the home.
The Wake County Sheriff's Office has not identified the people involved in the incident but neighbors told ABC11 Edward Mattison II and Tatiana Irvin-Mattison lived at the home.
Records show the couple bought the home in 2012
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The sheriff's office said CCBI and the Medical Examiner's Office have been called in to assist the investigation.
Deputies said a motive has not been determined for the shooting.