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It happened Saturday morning at the intersection of Person and Peace streets.
It happened at the intersection of New Bern Avenue and Columbia River Lane.
The Highway Patrol said Jared Logan was going more than 100 mph when he rear-ended a Cleveland County ambulance making a U-turn.
The team was returning to Fayetteville after participating in a 7-on-7 football scrimmage against South Brunswick High School.
Raleigh police say the 70-year-old driver accused of causing the crash is facing numerous charges.